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  HomeContents of Chinese Journal of Mechanical Engineering (English Edition),2002 No.2MICROSTRUCTURE CHARACTERIZATION OF LiCoO2 COATINGS FOR MOLTEN CARBONATE FUEL CELLS COMPONENTS
MICROSTRUCTURE CHARACTERIZATION OF LiCoO2 COATINGS FOR MOLTEN CARBONATE FUEL

 CELLS COMPONENTS*

 

Chen Wenzhe

College of Materials Science and Engineering, Fuzhou University

Klein Lisa

Rutgers University, USA

Huang Chaoming

Evercel Co. Connecticut, USA

 

Abstract: The sol-gel process, using aqueous solutions is used for dip coating onto substrates of 316L stainless steel. A suitable coating of LiCoO2 is achieved by varying the thickness and heat treating at 650℃ for 3h. Thermal analysis, X-ray diffraction analysis and SEM are carried out to characterize the microstructure of the coatings. The results show that the coating transforms from an amorphous gel to crystalline phases above 350℃, and show a porous structure. The phase transition mechanism is discussed.

Key words: Molten carbonate fuel cells  Sol-gel LiCoO2 coating  Crystalline phase transition


* This project is supported by Energy Research Corp., USA. Selected from Proceedings of 2000 the First International Conference on Mechanical Engineering; revised manuscript June 6, 2001

 

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